Interacting Glazes

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The inlay glaze is high in sodium, zinc, and titanium. The matrix glaze is high in alkaline earths,
particularly calcium, and also containing both barium and strontium. Quite a mix of diverse chemicals to
encourage a range of chemical reactions.

The inlay glaze contains nickel, cobalt and rutile.

In the inlay we see radiating bands of distinct colors and textures. At the center, a mixed chartreuse/yellow
with blue overtones. It is dominated by sheaves of needle like crystals, likely zinc. Next is a band of white
spherulitic bodies, then a band of blue, with seemingly blue tinged sperulites. These blue spherulites
are seen through a blue surface and are not themselves blue. The deep blue fades into the matrix glaze
which can be seen to have a distribution of the spherulites for some distance.

The nickel in the inlay glaze seems not to diffuse a great distance, with cobalt diffusing the furthest, showing
its characteristic color far past the original inlay masks. I attribute the white spherulites to titanium, which
don't take up either the nickel or cobalt.

While the matrix glaze contains some titanium, an unknown large quantity of rutile was added to the inlay glaze.

The background glaze is woof-hank; the inlay design is glazed with cooper_404_1Na_Z45.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze woof-hank and inlay glaze cooper_404_1Na_Z45

bowl is ~7 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula woof-hank :

K2O        0.11
Na2O       0.04
CaO        0.60
MgO        0.09
BaO        0.07
SrO        0.09

Al2O3      0.43

SiO2       2.9
P2O5       0.01
TiO2       0.05

molecular percent Silica 66.3%



Inlay Glaze:

Empirical Formula cooper_404_1Na_Z45:

K2O        0.07
Na2O       0.39
CaO        0.02
MgO        0.02
BaO        0.13
ZnO        0.37

Al2O3      0.40

SiO2       2.33
TiO2       0.15

molecular percent Silica 62.3%

Added:

~2% Cobalt Carbonate
1.5% Nickel Oxide
~8% Rutile



Remarks

The matrix glaze, woof-hank, is a fluid high gloss glaze, which is crazed so uninteresting in its own right,
yet so very fluid that it allows rapid diffusion of oxides. The result, it provides a medium for fascinating
effects.

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