reacting Glazes

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The matrix glaze is high in zinc and even higher in alkali metals. Its surface is covered in needle-shaped zinc
crystals. It is a micro-crystalline matte glaze featuring two shades of green crystalline inclusions in a yellow
ground.

The inlay glaze is high in silica and alkaline earths and a full gloss. The thin ribbon of this high silica
inlay glaze eats into the background glaze, creating a wide swath in which floes of half-disolved matrix
crystals float.

The background glaze is cooper_404_1Na_Z45_MZn; the inlay design is glazed with oribe-woof-MAlk-PPSi. It
had cobalt and Zircopax added casually, that is a splash, not measured.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze cooper_404_1Na_Z45_MZn and inlay glaze oribe-woof-MAlk-PPSi

bowl is ~7 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula cooper_404_1Na_Z45_MZn :

K2O        0.08
Na2O       0.41
CaO        0.02
MgO        0.01
BaO        0.16
ZnO        0.31

Al2O3      0.41

SiO2       2.4

molecular percent Silica 63.1%

added:

1.5% nickel oxide



Inlay Glaze:

Empirical Formula oribe-woof-MAlk-PPSi:

K2O        0.08
Na2O       0.03
CaO        0.72
MgO        0.17

Al2O3      0.29

SiO2       3.45
P2O5       0.01

molecular percent Silica 72.5

Added:

2% Cobalt Carbonate
5.0% Copper Oxide
5% Zircopax



Remarks

The inlay interaction region shows a region of what appears to be liquid-liquid phase separation
- a cloudy irregular flow not seen in either glaze separately.

Oil and vinegar salad dressing are comprised of two liquids which don't mix this is two distict liquid phases.
The opalescence of chun glazes is the result of the occurance of liquid-liquid phase separaction.

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