reacting Glazes

The background glaze is cooper_404_1Na_Z45_MZn; the inlay desig is glazed with hiAlk_Z3P_MAl.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The matrix glaze is high in zinc yet contains almost no calcium. It does contain nickel, whose color
is highly sensitive to the presence of calcium. Its surface is covered in needle-shaped zinc crystals.
It is a micro-crystalline matte glaze featuring two shades of green crystalline inclusions
in a yellow ground. The blue/green markings are most prominent where the glaze is thickest.

The inlay glaze is high in alumina and contains titanium, resulting in a stiff glaze with rutile crystals.
This inlay glaze contains calcium. which diffuses into the matrix glaze creating a band of
nickel brown surrounding the inlay.

For contrast we see the same matrix glaze cooper_404_1Na_Z45_MZn with a different inlay glaze,
oribe-woof-MAlk-PPSi here.

In contrast to what is seen in the prior note, here the matrix glaze has unhealed blisters, resulting from
an overgenerous glaze application. This glaze is a work in progress, so very sensitive to application thickness.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze cooper_404_1Na_Z45_MZn and inlay glaze hiAlk_Z3P_MAl

bowl is ~7 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula cooper_404_1Na_Z45_MZn :

K2O        0.08
Na2O       0.41
CaO        0.02
MgO        0.01
BaO        0.16
ZnO        0.31

Al2O3      0.41

SiO2       2.4

molecular percent Silica 63.1%



added:

1.5% nickel oxide

Inlay Glaze:

Empirical Formula hiAlk_Z3P_MAl :

K2O        0.12
Na2O       0.51
CaO        0.35
MgO        0.02

Al2O3      0.60

SiO2       3.28
P2O5       0.06
TiO2       0.22

molecular percent Silica 63.4%



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