Glaze Reactions

The background glaze is glossy, aqua tinted, blue-black with a prominent dusting of sharply delimited
white micro-crystalline inclusions.

The inlay glaze has eaten its way into the matrix glaze, many times the width of the original masks.
From the center out to the edge there are successive bands of metallic silvery grey in two shades,
then brown, orange and a mixture of aqua and blue.

The variation in rates of diffusion of the titanium and alkali metals from the inlay into the matrix,
and cross diffusion of silica into the inlay creates the banded pattern seen.

A variant of this glaze, with the same inlay glaze, has been seen previously here.

The glaze seen here, oribe-woof-black-M is lower in alumina and higher in silica than the prior glaze.

Both glazes are low in alkali metals and high in alkaline earths. A small shift in the Silica:Alumina
ratio has created a large shift in the texture of the glaze, this glaze is a full gloss, the other a waxy matte.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The background glaze is oribe-woof-black-M; the inlay design is glazed with hiAlk_Z3P_MAl.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze oribe-woof-black-M and inlay glaze hiAlk_Z3P_MAl

bowl is ~7 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula oribe-woof-black-M :

K2O        0.10
Na2O       0.04
CaO        0.69
MgO        0.17

Al2O3      0.38

SiO2       3.15
P2O5       0.01
ZrO2       0.05

molecular percent Silica 68.4%

added:

5% black copper oxide

0.75% cobalt carbonate



Inlay Glaze:

Empirical Formula hiAlk_Z3P_MAl :

K2O        0.12
Na2O       0.51
CaO        0.35
MgO        0.02

Al2O3      0.60

SiO2       3.28
P2O5       0.06
TiO2       0.22

molecular percent Silica 63.4%



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