Magnesium vs. Calcium

Decreased Magnesium results in the appearance of metallic micro-crystals and a more fluid melt.

The second glaze was generated from the first by replacing Dolomite with Bone Ash, which increased the surface coverage by
metallic micro-crystals, while simultaneously eliminating a colorful range of in-homogeneities.

Glaze satIron_ZG_1S_1Munge_3

The glaze with high MgO

A variegated opaque waxy matte glaze with black, red, and orange markings in a tan matrix.

full view

full view

bowl is ~4 inches in diameter



Glaze satIron_ZG_1S_1Munge_1Munge_3MMg_0

glaze with less MgO, and slightly higher P2O5.

Where thick, this glaze is covered with metallic micro-crystals in a glossy orange-y brown matrix. An even thicker application gives dense
black leopard spots. As a result of a thinner glaze application, the outside of the pot is dark brown with a
scattering of micro-crystals.

full view

full view

bowl is ~4 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2300 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula glaze satIron_ZG_1S_1Munge_3 :

K2O        .2
Na2O        .42
Li2O        .19
CaO        .1
MgO        .09

Al2O3        .5
Fe2O3        .18

SiO2        2.94
P2O5        .12

molecular percent Silica 61%



Empirical Formula Glaze satIron_ZG_1S_1Munge_3MMg_0

K2O        .2
Na2O        .43
Li2O        .2
CaO        .16
MgO        .01

Al2O3        .51
Fe2O3        .19

SiO2        3
P2O5        .16

molecular percent Silica 61%



Remarks

The effect on the appearance of the glaze of replacing MgO with CaO, and slightly increasing P2O5, is substantial.

The higher MgO glaze satIron_ZG_1S_1Munge_3, has large pinholes where thickly applied, and incompletely-healed bubbles on the rim.
These defect can be attributed to high viscosity, and a glaze on the edge of being underfired.

To what is attributed the appearance of the metallic micro-crystals in satIron_ZG_1S_1Munge_3MMg_0?
Replacing Dolomige with Bone Ash both replaced MgO with CaO and increased P2O5, I attribute the greater part of the change
to the increased CaO, which results in a more fluid and uniform melt. The greater fluidity of the lower MgO melt,
satIron_ZG_1S_1Munge_3MMg_0, facilitates the growth of the golden metallic micro-crystals.
By contrast, in the higher MgO melt, more immiscible components are present, generating distinct colors and textures.

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