Magnesium vs. Calcium

A prominent opaque second phase in a clear glaze nearly dissapears with increased Magnesium.

The second glaze has more Magnesium and less Calcium than the first glaze.



Glaze alkTi_ZQ_2

The glaze with high Calcium, low Magnesium.

A transparent pale white glaze with prominent opaque white inclusions.

full view

full view

bowl is ~4 inches in diameter



Glaze alkTi_ZQ_3

glaze with lower CaO, and higher MgO

Glaze is a pale purple-y off white with flecks of the white crystals so prominent in alkTi_ZQ_2.

full view

full view

bowl is ~4 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 2050 deg F

120 deg F an hour to 2295 deg F with a hold of 30 minutes at 2295 def G

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Empirical Formula glaze alkTi_ZQ_2 :

K2O        .13
Na2O        .23
Li2O        .26
CaO        .31
MgO        .07

Al2O3        .51

SiO2        4.3
TiO2        0.2

molecular percent Silica 72%



Empirical Formula Glaze alkTi_ZQ_3

K2O        .13
Na2O        .23
LI2O        .26
CaO        .06
MgO        .32

Al2O3        .51

SiO2        4.3
TiO2        .2

molecular percent Silica 72%



Remarks

The effect on the appearance of the glaze of replacing some CaO with MgO is a surprise. The second glaze with higher MgO is less viscous,
not the expected result from either increasing MgO, nor decreasing CaO.

The crazing of the second glaze is the result of the low CaO. Reducing the alkali metals and increasing the CaO might remedy this defect,
while retaining a similar look and feel of the glaze.

The low MgO higher CaO glaze, alkTi_ZQ_2, has a thick roll of glaze at its foot. This is an indication of a more viscous glaze.

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