unrelated glazes at a vertical interface

Dissimilar glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.
The original mask for the inlay was a curved line, nowhere more than three eights of an inch thick.

The matrix glaze is high in alkaline earths, Calcium and Magnesium. The inlay glaze, by contrast,
is higher in alkali metals and Iron, and contains substantial Phosphorus.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is iron_Alex_1_1PSi, the inlay design is glazed with satIron_ZG_1S_1Munge_3MMG_0.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view --



Image of the piece

full view

mug with glaze iron_Alex_1_1PSi and inlay satIron_ZG_1S_1Munge_3MMg_0

mug is ~4.5 inches in high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula iron_Alex_1_1PSi :

K2O        0.09
Na2O       0.26
Li2O       0.09
CaO        0.42
MgO        0.14

Al2O3      0.51
Fe2O3      0.13

SiO2       3.28
P2O5       0.02

molecular percent Silica 66.3%



Inlay Glaze

Empirical Formula satIron_ZG_1S_1Munge_3MMg_0:

K2O        0.20
Na2O       0.43
Li2O       0.20
CaO        0.16
MgO        0.01

Al2O3      0.51
Fe2O3      0.19

SiO2       2.97
P2O5       0.17

molecular percent Silica 61.5%



Remarks

The higher concentrations of alkali metals and Phosphorus migrate from the inlay glaze into the matrix, seeding
additional phases in the matrix glaze.

In the interaction region, we see visible yellow acyclic crystals on a dark glossy background. These crystals
are also present in the matrix glaze iron_Alex_1_1PSi, yet are small, so unnoticed.

The glossy black phase seen in the interaction region is not otherwise seen in either of these glazes.

Most of the increase in area covered by the inlay is attributable to dissolution of the matrix glaze
resulting from diffusion of inlay glaze into the matrix.

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