Increasing Silica

The effect of increasing Silica in an oil spot glaze.

here I showed a glaze which with more silica was transformed into an oil spot glaze.

So I wondered what the effect of increasing silica would be on an oil spot glaze.

The glaze longquan_iron_mashiko_0 is an oil spot glaze, black with silvery oil spots. I increased the silica in
that glaze to get the glaze longquan_iron_mashiko_0_PSi.

If the glaze is applied thickly, the resulting oil spots are larger and cover more of the surface. If that glaze
is applied thin, the oil spots take over, producing a silver metallic glaze, as is seen on the outside of the bowl.



Image of the low silica glaze longquan_iron_mashiko_0

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



Image of the high silica glaze longquan_iron_mashiko_0_PSi

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a 50 min hold at 1750 deg F

50 deg F an hour to 1700 deg F then a three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula longquan_iron_mashiko_0 :

K2O        0.11
Na2O       0.45
Li2O       0.15
CaO        0.11
MgO        0.18

Al2O3      0.71
Fe2O3      0.19

SiO2       4.27

molecular percent Silica 69%



Empirical Formula longquan_iron_mashiko_0_PSi :

K2O        0.11
Na2O       0.45
Li2O       0.16
CaO        0.11
MgO        0.17

Al2O3      0.72
Fe2O3      0.20

SiO2       4.72

molecular percent Silica 71%



Remarks

The small differences in the non-silica components of the empirical formula are an artifact of the method
used to increase silica. I added silica to the glaze longquan_iron_mashiko_0, then normalized the recipe to add to 100.

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