Glazes reacting at a vertical interface

The matrix (i.e. background) glaze and inlay glaze do not overlap before firing.

The matrix is a high alkali metal, saturated iron glaze. The inlay glaze is lower in alkali metals,
and contains no added iron. Both matrix and inlay glaze contain some phosphorus.

The original inlay masks were continuous curves between three eights of an inch and half an inch thick.
The yellow color visible in the inlay is entirely the result of diffusion of iron from the matrix glaze into
the inlay glaze.

Several closeups of the interaction region of the two glazes are shown, and additionally for context,
a picture of the pot is shown.

The background glaze is satIron_ZG_0, the inlay design is glazed with
iron_Alex_1_1MFe.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view

full view



Image of the piece

full view

pasta bowl with glaze satIron_ZG_0 and inlay glaze iron_Alex_1_1MFe

bowl is ~10 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

200 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a 50 minute hold at 1750 deg F

300 deg F an hour to 1700 deg F then a three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula satIron_ZG_0 :

K2O        0.10
Na2O       0.49
Li2O       0.19
CaO        0.16
MgO        0.06

Al2O3      0.59
Fe2O3      0.20

SiO2       3.14
P2O5       0.04

molecular percent Silica 63%



Inlay Glaze

Empirical Formula iron_Alex_1_1MFe

K2O        0.09
Na2O       0.27
Li2O       0.09
CaO        0.45
MgO        0.10

Al2O3      0.51

SiO2       2.9
P2O5       0.02

molecular percent Silica 65.4%

Added:

Cobalt Carbonate 1%
Copper Carbonate 0.5%



Remarks

In the close-up pictures one notes regions of inlay entirely absorbed by the interaction region.

Iron has diffused from the matrix glaze into the inlay glaze, and calcium in the opposite direction.

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