Iron Glaze with reflective surface film

A mirror-like thin film is seen on the surface of this saturated iron glaze. This film appears to be
composed of metallic-like micro-crystals, which precipitate out of the glaze onto its surface.
Probably these are some combination of magnetite and hematite as form in oil spot glazes.

The mechanism for the growth of a metallic oxide micro-crystalline surface film is likely the same as that of
the growth of micro-crystals on the surface of matte glazes. The concentration of the second phase component
exceeds its solubility limit within the glaze melt so it precipitates and plates out on the surface.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe with a needle applicator.



Image of the glaze satIron_ZT_Z3J

full view

view of the inside of the bowl

full view

Close up image of a section showing the reflective metallic film

bowl is ~ 6 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2170 deg F with a hold of 1 hour at 2170 deg F

120 deg F an hour to 2250 deg F

60 deg F an hour to 2270 deg F with a hold of 30 minutes at 2270 deg F

60 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a 4 hour hold at 1750 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula satIron_ZT_Z3J :

K2O        0.20
Na2O       0.16
CaO        0.44
MgO        0.20

Al2O3      0.6
Fe2O3      0.22

SiO2       3.08
P2O5       0.13

molecular percent Silica 61.2%



Empirical Formula inlay glaze inlay_Z3J_0 :

K2O        0.18
Na2O       0.78
CaO        0.02
MgO        0.02

Al2O3      0.69
Fe2O3      0.02

SiO2       2.28
P2O5       0.19

molecular percent Silica 54.5%



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