o Effect of Alternative Firing

Effect of Inverted Down-Firing

The clusters of surface micro-crystals in an iron-Titanium glaze morphs with an inversion of the order
of the downfire holds in the firing. The variety of colors and textures increases, while the size of the
clusters decreases.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.

Both Firing 1 and Firing 2 have the same upfire protocol.

Firing 1:

The downfire is my regular down firing, with holds at 1850 degF, 1750 degF, 1700 degF and 1650 degF.

Firing 2:

This is an 'invert' firing, following the procedures used by the glass ceramic folk, which is to drop low for neucleation of
crystals, i.e. crystal seeds, then come back up for the growth of the micro-crystals. In this case, the downfire
drops with a hold at 1650 degF, then rises back up with a hold at 1850 deg F, then back down with a hold at 1700 deg F.



Image of the glaze hiAlk_satIron in Firing 1

full view

inside



full view

close up

bowl is ~ 6 inches in diameter



Image of the glaze hiAlk_satIron in Firing 2

full view

inside



full view

close up

bowl is ~ 6 inches in diameter



oxidation firings to cone 10 in an electric kiln

Firing 1 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F



Firing 2 profile

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1650 deg F then a 3 hr hold at 1650 deg F

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1700 deg F then a 2 hr hold at 1700 deg F



Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula hiAlk_satIron:

K2O        0.06
Na2O       0.62
CaO        0.29
MgO        0.03

Al2O3      0.56
Fe2O3      0.10

SiO2       3.67
P2O5       0.08
TiO2       0.15

molecular percent Silica 66%



Inlay Glaze:

Empirical Formula inlay hiAlk_Z3P_Z3V_0:

K2O        0.18
Na2O       0.41
CaO        0.31
MgO        0.10

Al2O3      0.64

SiO2       3.54
P2O5       0.07
TiO2       0.21

molecular percent Silica 64.9%



Remarks

At what temperature do the crystal seeds, i.e. nuclei, form and at what temperature do they grow?
With both copper red glazes and iron red glazes, there are reports of getting the good color by refiring
in a bisque firing. The effect is to bring the glaze back up to melting
temperature after it has already cooled and solidified.

Centura by Corningware is an example of ceramics that are created by starting with glass that is
transformed by a process of nucleation and growth into a crystal. In that case, they drop the glass to a low
temperature to form the nuclei, then raise the temperature to grow the crystals.

Firing 2, the firing I refer to as the invert firing, follows that glass-crystal pattern in that it drops
low for a hold of several hours, then comes back up.

Here, the result is greater variety of colors and textures, a shift in balance of color, and in the
size of the resulting crystal clusters.

Carol's Home Page