Glaze Reactions

The matrix glaze satIron_ZG_Z3N_Z4A_0, is a saturated iron glaze with large, diffuse leopard spots.

The inlay sits atop a diffuse band of mixed silvery gunmetal and orange matrix glaze.

The interaction region frames an abstract turquoise spiral, having bands of deep brooding glossy
black and iron-yellow streaks of foam. It stands atop a diffuse gunmetal band, which fades
into the matrix glaze.

A similar leopard spot glaze with related inlay glazes is seen here:

Small differences in both inlay glaze and matrix glaze result in a dominant design and a frame
that recedes into the background rather than upstaging the design.

The matrix (i.e., background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The background glaze is satIron_ZG_Z3N_Z4A_0; the inlay design is glazed with oribe-woof-PAl-PSiMg, and
oribe-woof-PAlk.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

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Image of the piece

full view

bowl with glaze satIron_ZG_Z3N_Z4A_0

bowl is ~6 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula satIron_ZG_Z3N_Z4A_0 :

K2O        0.14
Na2O       0.56
CaO        0.28
MgO        0.02

Al2O3      0.69
Fe2O3      0.23

SiO2       3.65
P2O5       0.07

molecular percent Silica 64.6%



Inlay Glazes:

Empirical Formula oribe-woof-PAl-PSiMg:

K2O        0.10
Na2O       0.04
CaO        0.61
MgO        0.25

Al2O3      0.35

SiO2       3.29
P2O5       0.01

molecular percent Silica 70.58%

Added:

5.0% Copper Oxide



Empirical Formula oribe-woof-PAlk:

K2O        0.16
Na2O       0.05
CaO        0.64
MgO        0.15

Al2O3      0.29

SiO2       2.70
P2O5       0.01

molecular percent Silica 67.47%

Added:

5.0% Copper Oxide



Remarks

The matrix glaze seen here, satIron_ZG_Z3N_Z4A_0 has slightly lower alumina, and slightly higher
alkali metal:alumina ratio than that of the prior note satIron_Zg_Z3N_EPK, and as a result is more fluid.
This is seen in the form taken by its leopard spots. Here the bubbles which burst to form the leopard
spots are larger, as they were able to expand to a greater size in a more fluid glaze. These larger bubbles
burst leaving only their perimeter.

There are two inlay glazes, one of which also has lower alumina and is also as a result more fluid.

A more fluid inlay in a more fluid matrix, allows the inner part of the inlay to expand. More,
the interaction with the matrix glaze isn't dominated by the copper, other oxides interacted as well,
so that the brooding dark band of copper in the matrix glaze isn't as dominant as in the prior example.

Nearly inconsequential differences in both the inlay and matrix glazes shift the final
appearance considerably.

The leopard spots are matte black iron micro-crystals, they are a second phase which formed in the glaze.
Formed by a different mechanism than the coppery colored micro-crystals seen on the rim, but same phenomenon,
a different phase. Each phase has its own colors, the leopard spots matte black. The iron distributes
itself differently in each phase.

The leopard spots form by an interesting mechanism - bubbles form in the glaze. Those bubbles have
a surface, just as the surface of the glaze, an interface between glaze and gas. the black micro-crystals
grow on the bubble surface, when the bubble reaches the glaze surface and bursts, those micro-crystals
remain as relics of the bubbles.

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