Glaze Reactions

The background glaze is a composite, with a surface of micro-crystalline clusters atop a full gloss
cobalt blue substrate.

The inlay glaze is a titanium matte with its own distinct micro-crystalline clusters.

The matrix (i.e. background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The background glaze is zincSr_Z3TV_0_lAlk; the inlay design is glazed with hiAlk_Z3P_MAl.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze zincSr_Z3TV_0_lAlk and inlay glaze hiAlk_Z3P_MAl

bowl is ~7 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula zincSr_Z3TV_0_lAlk :

K2O        0.10
Na2O       0.41
CaO        0.03
MgO        0.27
SrO        0.12
ZnO        0.07

Al2O3      0.5

SiO2       2.75

molecular percent Silica 64.7%

added:

2.5% cobalt Carbonate



Inlay Glaze:

Empirical Formula hiAlk_Z3P_MAl :

K2O        0.12
Na2O       0.51
CaO        0.35
MgO        0.02

Al2O3      0.60

SiO2       3.28
P2O5       0.06
TiO2       0.22

molecular percent Silica 63.4%



Remarks

The original inlay design was a continuous spiral. As the inlay glaze diffuses into the background glaze,
it moves most easily through the glassy substrate, but it is impeded by the micro-crystalline cluster
within the background glaze. The rhythmic indentations seen are where crystal clusters have blocked
its movement.

The oxides of the background glaze and inlay glaze diffuse into each other, and the micro-crystals of
background glaze block those of the inlay. Conversely the crystals in the inlay glaze block movement of the
background glaze.

The green edge seen between the inlay glaze and background glaze is the interaction of cobalt and titanium.

The intricate pattern created by the interaction of these two glazes is the result of the non-uniformity
of the glazes. Both the background glaze and inlay glaze are multi-phase assemblages. Each phase of
each glaze reacts distinctly with the several phases of the other.

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