Saturated Iron

Here are two near neighbor saturated iron glazes, satIron_ZG_7_MliAlk and satIron_ZG_7_MLi.

The second glaze has lower silica, higher alkali metals, higher phosphorus and lower magnesium. The second
glaze is an iron red, the coppery colored micro-crystalline clusters so prominent in the first glaze
are entirely gone.



Image of the glaze satIron_ZG_7_MLiAlk

full view

inside

full view

outside

bowl is ~3.5 inches in diameter



Image of the glaze satIron_ZG_7_MLi

full view

inside

full view

outside

bowl is ~3.5 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze compositions

Empirical Formula satIron_ZG_7_MLiAlk:

K2O        0.07
Na2O       0.56
CaO        0.23
MgO        0.14

Al2O3      0.51
Fe2O3      0.21

SiO2       3.51
P2O5       0.04

molecular percent Silica 66.5%



Empirical Formula satIron_ZG_7_MLi :

K2O        0.06
Na2O       0.62
CaO        0.21
MgO        0.10

Al2O3      0.51
Fe2O3      0.21

SiO2       3.05
P2O5       0.11
TiO2       0.01

molecular percent Silica 62.47%



Remarks

The first glaze is variegated, with a black matrix and several distinct micro-crystalline inclusions.
It also is significantly glossier that the second glaze. The increased silica in this glaze decreased
the viscosity of the glaze thus allowing a greater variety of second phase crystals to grow.

The second glaze contains trace amounts of titanium, which interacts with iron to produce a characteristic
iron titanate color, more this glaze is significantly higher in phosphorus than the first glaze.
The color is a mixture of several shades of orange and iron red, with a bit of that monkey vomit green.
The inside of the bowl has a substantially heavier coat of glaze, and the oranges and browns dominate.
The red dominates only where the glaze is thin.

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