Glaze Reactions

The background (matrix) glaze is hiAlk_Z3P_Z4A_PF; the inlay design is glazed with
oribe-woof-PAl-PSiMg. The matrix glaze is a titanium microcrystalline matte glaze with snow flakes.

A previous pot seen seen here: is glazed with a related high titanium glaze, hiAlk_Z3P_Z4A, and
the same inlay glaze. That glaze, hiAlk_Z3P_Z4A, has higher Alumina, and as a result is stiffer.

Here, the background glaze hiAlk_Z3P_Z4A_PF, with slightly less alumina than hiAlk_Z3P_Z4A,
shows a fluid substrate, and disconnected rutile micro-crystalline clusters, which I have characterized
as snow flakes. This in contrast to the dense micro-crystalline matte glaze hiAlk_Z3P_Z4A, in
which no glassy regions are seen.

Relics of these micro-crystalline clusters, the snow flakes, are seen as isolated dark disks
in the interaction region.

The inlay glaze diffuses into the background glaze, and reacts with the fluid substrate to
produce an amber glassy region with scattered shaggy irregular greyish-white micro-crystals.

The matrix (i.e., background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

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Image of the piece

full view

bowl with glaze hiAlk_Z3P_Z4A_PF and inlay oribe-woof-PAl-PSiMg

bowl is ~6 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a white stoneware from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula hiAlk_Z3P_Z4A_PF :

K2O        0.11
Na2O       0.48
CaO        0.39
MgO        0.02

Al2O3      0.55

SiO2       2.95
P2O5       0.06
TiO5       0.21

molecular percent Silica 61.9%



Inlay Glaze:

Empirical Formula oribe-woof-PAl-PSiMg:

K2O        0.10
Na2O       0.04
CaO        0.61
MgO        0.25

Al2O3      0.35

SiO2       3.29
P2O5       0.01

molecular percent Silica 70.58%

Added:

5.0% Copper Oxide



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