Calico

The glaze shown here cooper_404_1Na_PZn, is stunning... and dunted. It is high in ZnO, yet many glazes
are equally high in ZnO and don't dunt. For comparison we show three of them here. are three of them.

Replacing some BaO with SrO gives the glaze cooper_404_1Na_PZn_PSr. Alternatively increasing
the silica gives the glaze cooper_404_1Na_PZn_PSi. Last is the glaze cooper_404_1Na_Z4E_1 which
has lower alkali metals and higher silica.

Many of the calico family of glazes feature a glossy amber phase out of which the crystals grow.
This phase is visible in both cooper_404_1Na_PZn_PSr, and cooper_404_1Na_PZn_PSi,
yet seems not present in the glaze cooper_404_1Na_PZn.

It seems that cooper_404_1Na_PZn has greater crystal fraction in the final melt, which causes it
to have lower thermal expansion, perhaps the cause of its dunting. Is the lack of the amber fluid phase
the cause of the greater micro-crystal growth?

cooper_404_1Na_Z4E_1 has a pale pink matrix, and steel blue micro-crystals which have sharp contrast
with the pink, but are small. The crystal content of this glaze seems low compared to other of the
calico glazes, perhaps in this case that accounts for it not dunting.



Image of the glaze cooper_404_1Na_PZn

full view

inside

full view

outside

bowls is ~6 inches in diameter



Image of the glaze cooper_404_1Na_PZn_PSr

full view

inside

full view

outside



Image of the glaze cooper_404_1Na_PZn_PSi

full view

inside

full view

outside



Image of the glaze cooper_404_1Na_Z4E_1

full view

inside

full view

outside



except otherwise noted bowls are ~3.5 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze compositions

Empirical Formula cooper_404_1Na_PZn :

K2O        0.07
Na2O       0.26
CaO        0.04
MgO        0.01
BaO        0.20
ZnO        0.42

Al2O3      0.32

SiO2       2.37

molecular percent Silica 64.2%

added:

1.5% Nickel Oxide



Empirical Formula cooper_404_1Na_PSr :

K2O        0.07
Na2O       0.17
CaO        0.04
MgO        0.01
BaO        0.20
SrO        0.09
ZnO        0.42

Al2O3      0.32

SiO2       2.38

molecular percent Silica 64.2%

added:

1.5% Nickel Oxide



Empirical Formula cooper_404_1Na_PSi :

K2O        0.07
Na2O       0.26
CaO        0.04
MgO        0.01
BaO        0.20
ZnO        0.42

Al2O3      0.33

SiO2       2.74

molecular percent Silica 67.3%

added:

1.5% Nickel Oxide



Empirical Formula cooper_404_1Na_Z4E_1:

K2O        0.06
Na2O       0.14
CaO        0.03
MgO        0.01
BaO        0.34
ZnO        0.42

Al2O3      0.33

SiO2       2.83

molecular percent Silica 68%

added:

1.5% Nickel Oxide



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