More Snow Flake

Here are three snowflake glazes (glazes containing rutile micro-crystalline clusters). These glazes
hiAlk_Z3P_Z3E_0, hiAlk_Z3P_Z3E, and hiAlk_Z3P_Z3E_1, will be referred to as glaze #1, glaze #2
and glaze #3.

The degree to which the rutile micro-crystals dominate the appearance varies substantially more than
the difference in composition.

If applied thickly, glaze #1 shows a flat white micro-crystalline surface with only hints of a transparent
substrate. The micro-crystalline clusters merge over much of the surface of the pot.

Glaze #2 exhibits a translucent surface with a lacy network of micro-crystalline threads,
overlaid by micro-crystalline assemblages that are comprised of shaggy mounds that mimic
appearance of the floppy wet snow which falls near freezing when the weather isn't decided, snow
vs. rain.

Glaze #3 has tight micro-crystalline clusters in a large clear translucent glassy ground.

The most prominent difference in composition is the silica:alumina ratio:

hiAlk_Z3P_Z4E_0     5.18
hiAlk_Z3P_Z3E       5.43
hiAlk_Z3P_Z4E_1     5.85

One can speculate that low silica alumina ratio so decreases solubility of the crystalline phase that
like sugar in cold coffee, it is forced out.

Additionally, the lower alumina of hiAlk_Z3P_Z4E_1 increases the fluidity of the glaze enhancing the
ability of the crystal forming species to flock together in the glaze.



Image of the glaze hiAlk_Z3P_Z3E_0

full view

inside

full view

outside



Image of the glaze hiAlk_Z3P_Z4E

full view

inside

full view

outside



Image of the glaze hiAlk_Z3P_Z4E_1

full view

inside

full view

outside



bowls are ~3.5 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile cone 10

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hour hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze compositions

Empirical Formula hiAlk_Z3P_Z4E_0 :

K2O        0.10
Na2O       0.48
CaO        0.40
MgO        0.02

Al2O3      0.58

SiO2       2.98
P2O5       0.06
TiO2       0.21

molecular percent Silica 61.7%



Empirical Formula hiAlk_Z3P_Z4E :

K2O        0.11
Na2O       0.50
CaO        0.37
MgO        0.02

Al2O3      0.57

SiO2       3.11
P2O5       0.06
TiO2       0.22

molecular percent Silica 62.7%



Empirical Formula hiAlk_Z3P_Z4E_1 :

K2O        0.11
Na2O       0.48
CaO        0.39
MgO        0.02

Al2O3      0.55

SiO2       3.21
P2O5       0.06
TiO2       0.22

molecular percent Silica 63.7%



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