Glaze Reactions with a rutile inlay

A glossy black iron glaze containing cobalt, with silvery micro-crystalline inclusions, has an inlay
glaze containing rutile. The resulting design exhibits a multitude of iron colors in an intricate lacy pattern.

The matrix (i.e., background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The background glaze is oribe-satIron; the inlay design is glazed with hiAlk_Z3P_Z3V_0

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.

The close-up images were heavily edited to enhance detail and colors are brighter as a result.
The colors of the full image of the bowl are as they appear in bright light.



Close up Images of the interaction region

full view

full view

full view

full view

full view



Image of the piece

full view

full view

bowl with glaze oribe-satIron and inlay glaze hiAlk_Z3P_Z3V_0_PTi

bowl is ~6 inches in diameter



oxidation firing to hot cone 10 in an electric kiln

Firing profiles

Up Fire profile hot cone 10

150 deg F an hour to 250 deg F

300 deg F an hour to 1800 deg F

200 deg F an hour to 2050 deg F

120 deg F an hour to 2320 deg F with a hold of 20 minutes at 2320 deg F

Down Fire Profile hot cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hr hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula oribe-satIron :

K2O        0.15
Na2O       0.28
CaO        0.39
MgO        0.18

Al2O3      0.52
Fe2O3      0.21

SiO2       3.39
P2O5       0.05

molecular percent Silica 65.57%

Added:

5.0% cobalt carbonate



Inlay Glazes:

Empirical Formula hiAlk_Z3P_Z3V_0_PTi

K2O        0.17
Na2O       0.41
CaO        0.32
MgO        0.10

Al2O3      0.63

SiO2       3.50
P2O5       0.07
TiO2       0.39

molecular percent Silica 62.6%



Remarks

Rutile alters colors; the green seen faintly in the inlay is the result of the interaction of rutile
from the inlay glaze and cobalt from the background glaze. The orangy-gold color of the crystals
seen framing the edge of the inlay in the first close-up are the effect of rutile on iron.

The various shades of brown are iron colors. The red seen in the lower part of the third closeup
image is an iron red, a most illusive color; showing itself only within tight constraints.

The background glaze has a cellular structure of abutting micro-crystalline clusters, edged by, and
not quite separated by the glossy black underlying glassy matrix.

It is this glassy matrix which is most readily invaded by the downward flowing, thickly applied
inlay glaze. This flowing around the curved microcrystalline clusters produced the striated
pattern of the large ovoids of mixed inlay and background glaze.

Carol's Home Page