Glaze Reactions in an altered firing

The matrix glaze and inlay glaze shown here were seen previously here:

This is an exploration of a firing which has a slow up-fire in addition to having the usual holds
on the way down. In order for crystals to grow in a glaze, the oxides which will grow the crystals must
first dissolve into the glaze matrix. Here, by contrast with the prior results, by giving the glaze
additional time to melt on the way up, crystals are seen to have grown both in the inlay itself, and
in the interaction zone of the inlay and background glaze.

An iron matrix glaze, with silvery micro-crystalline inclusions, has a glossy blue-green inlay. The
resulting design has fragments of glassy blue edged in contrasting dendritic crystals. In addition,
acyclic snowflake-like crystals are seen in the inlay glaze.

The matrix (i.e., background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three quarters of an inch, is considerably thicker than my
usual inlay.

The background glaze is oribe-satIron; the inlay design is glazed with oribe-woof-PAlkAl-PSiMg

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.

The close-up images were heavily edited to enhance detail and colors are brighter as a result.
The colors of the full image of the bowl are as they appear in bright light.



Close up Images of the interaction region

full view

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze oribe-satIron and inlay glaze oribe-woof-PAlkAl-PSiMg

bowl is ~6 inches in diameter



oxidation firing to almost cone 11 in an electric kiln

Firing profiles

Up Fire profile hot cone 10

150 deg F an hour to 250 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2250 deg F then a 1 hr hold at 2250 deg F

90 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile hot cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hr hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula oribe-satIron :

K2O        0.15
Na2O       0.28
CaO        0.39
MgO        0.18

Al2O3      0.52
Fe2O3      0.21

SiO2       3.39
P2O5       0.05

molecular percent Silica 65.57%

Added:

5.0% cobalt carbonate



Inlay Glazes:

Empirical Formula oribe-woof-PAlkAl-PSiMg:

K2O        0.17
Na2O       0.05
CaO        0.49
MgO        0.29

Al2O3      0.35

SiO2       3.3
P2O5       0.01

molecular percent Silica 70.68%

Added:

5.0% Copper Oxide



Remarks

This firing features a 'rounded at the top' firing profile; with a hold of an hour 60 degreesF
below top temperautre, and a slow climb from there to the top temperature.

The results in this firing are distinct; the sharp pointed edges indicate crystal growth,
as do the large 'snowflake-like' features seen in the inlay.

The inlay was three quarters of an inch in width that, together with a liberal inlay glaze application,
caused substantial flows of the inlay through the background glaze. The shape of this inlay differs
from that seen in the previous note and accounts for some of the differences in the appearance of the
inlay and interaction region. That said, The large flat snowflake-like crystals seen in the inlay are new to
this firing.

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