Reactions at the interface between two glazes

The interaction at the interface of adjacent glazes.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is nepheline_Z1A_2MAlk, the foreground design is glazed with satIron_ZG_1O_1Q_1MFe

The design is created by adhering a mask and then applying the main glaze. After drying, the entire pot is coated in wax,
then the mask is removed and the open area filled in with a second glaze.

Previously I'd shown the glaze satIron_ZG_1O_1Q_1MFe as foreground glaze with background glaze:

satIron_ZG_1S_1Munge_1

and with background glaze:

satIron_ZG_4

and also with background glaze:

iron_8_R_C10_13PSi

Here, with the background glaze nepheline_Z1A_2MAlk, in contrast to the prior examples, the interaction region separates
along a boundary within the original masked region into two distinctive bands.

A thin black line resides within the masked region, having migrated inward from the original boundary of the design region.
On the background side of this line is a defuse froth of mixed red and yellow foam
with a scattering of silvery metallic crystals.



Close up Images of the interaction region

full view

full view

full view



Image of the piece

full view

bowl with glaze nepheline_Z1A_2MAlk and inlay satIron_ZG_1O_1Q_1MFe

bowl is ~9 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.

glaze compositions

Background glaze

Empirical Formula nepheline_Z1A_2MAlk :

K2O        .08
Na2O        .52
Li2O        .06
CaO        .11
MgO        .23

Al2O3        .73
Fe2O3        .22

SiO2        4

molecular percent Silica 67%



Inlay Glaze

satIron_ZG_1O_1Q_1MFe :

K2O        .24
Na2O        .22
Li2O        .24
CaO        .16
MgO        .14

Al2O3        .47
Fe2O3        .09

SiO2        3.17
P2O5        .04

molecular percent Silica 66%



Remarks

After firing, the area covered by the design mask is reduced somewhat, but its general shape is unchanged.

The inlay glaze is more fluid than the background glaze.

The fluid inlay glaze eats beneath the matrix glaze, and reacts with it to form the frothy yellow and red inclusions.

These are both high alkali metal glazes with similar silica. The background glaze nepheline_Z1A_2MAlk has
lower calcia, higher iron, magnesia, alumina and no phosphorus. It is more fluid
than I would have expected for its high alumina and relatively lower alkali metals.

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