disparate glazes at a vertical interface

Disparate glazes meeting at a vertical interface. The matrix (i.e. background) glaze and inlay glaze overlap
by no more than an eighth of an inch before firing, with no overlap whatever for large parts of the design.
The original mask for the inlay was a curved line, a scribble, and nowhere more than
half an inch across.

The matrix glaze is a high iron, high alkali metal glaze. The inlay glaze, by contrast,
is high in alkaline earths, particularly CaO, and lower in alumina.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is satIron_ZG_0, the foreground design is glazed with alexanderBowl_0_Z1Y.

A thick glaze application resulted in large crystals forming in the matrix glaze.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze satIron_ZG_0 and inlay alexanderBowl_0_Z1Y

bowl is ~9 inches in diameter



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula satIron_ZG_0 :

K2O        0.1
Na2O        0.49
Li2O        0.19
CaO        0.16
MgO        0.06

Al2O3        0.59
Fe2O3        0.20

SiO2        3.14
P2O5        0.04

molecular percent Silica 63%



Inlay Glaze

alexanderBowl_0_Z1Y :

K2O        .09
Na2O        .05
CaO        .70
MgO        .16

Al2O3        .43

SiO2        2.7

molecular percent Silica 65%

Added:

1% Cobalt Carbonate .67% Copper Carbonate



Remarks


Metallic micro-crystals appear in this glaze if applied thickly. Here we see acicular crystals growing
in the interfacial region distinct from its native metallic micro-crystals. These acicular crystals are reminiscent
of those seen in the glaze satIron_Ip7_5

As easter egg dye spreads by diffusion into the entire pot, the higher concentration of CaO
in the inlay glaze will migrate into the matrix, encouraging the creation of an additional crystalline phase
in the matrix glaze.

Most of the increase in area covered by the inlay is attributable to crystal growth in the matrix (background) glaze,
and diffusion of the inlay glaze into the matrix.

The mask for the inlay is a simple wiggly line. After firing, the inlay is considerably broadened.

The closeup images were enhanced to increase the visibility of the crystals. The yellow seen in
the inlay is the strong primary yellow as seen.

Carol's Home Page