Shifting Edges

Another glaze near iron_Alex_0 .

Previously we have seen:

iron_Alex_0PSiMAlk with higher silica and alumina that resulted in denser, but smaller versions of
iron_Alex_0's acicular crystals in a glossy matrix;

and iron_Alex_1 with lower alumina, but also lower alkali metals, which is a micro-crystalline matte glaze.

The glaze shown in this note, iron_Alex_2, is closest to iron_Alex_1, having the same alumina and silica
but higher alkali metals. In its empirical formula, CaO is replaced by alkali metals.

iron_Alex_2 has the acicular crystals in a glossy matrix seen in iron_Alex_0.



Image of the glaze iron_Alex_2

full view

inside



full view

outside

bowl is ~ 4 inches in diameter.



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Empirical Formula iron_Alex_2 :

K2O        0.10
Na2O       0.33
Li2O       0.13
CaO        0.34
MgO        0.10

Al2O3      0.53
Fe2O3      0.15

SiO2       2.96
P2O5       0.02

molecular percent Silica 63.6%



For reference the parent glaze:

Empirical Formula iron_Alex_1 :

K2O        0.07
Na2O       0.33
Li2O       0.12
CaO        0.38
MgO        0.10

Al2O3      0.53
Fe2O3      0.15

SiO2       2.97
P2O5       0.02

molecular percent Silica 63.5%



Remarks

iron_Alex_2 has very nearly the same empirical formula as iron_Alex_1, having only slightly higher alkali metals,
and slightly lower CaO. I attribute the difference in appearance to its higher alkali metals, because previous tests
that adjusted CaO ratios did not produce significant differences in glaze appearance..

iron_Alex_2 shows its fluidity by a slight drip of glaze at its foot.

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