Glaze Interactions

This is a further exploration of a firing which has a slow up-fire in addition to having the usual holds
on the way down.

The matrix glaze is a high titanium glaze which develops titanium micro-crystalline
clusters in a glossy matrix if applied thin, or is a micro-crystalline matte glaze if applied thickly.
The inlay glaze is oribe-woof-black-M. This is a high-silica/low-alumina glaze, which is a
full gloss glaze that develops small micro-crystal clusters.

As previously seen here, the copper migrates into the background glaze,
staining the titanium crystals brown or black depending on the degree of migration.

In addition, the slow up-fire allows micro-crystals, once formed in the matrix glaze, to migrate into
the inlay and, in some cases, continue to grow as titanium continues to diffuse into the inlay region
during the slow approach to top temperature. The micro-crystals which normally grow in the inlay glaze
will also act as sites for the growth of micro-crystals, explaining the occurrence of such a
profusion of distinct crystals.

Large acicular crystals are seen overlapping the matrix glaze and inlay in the first image. In the
second image a rather large mass of micro-crystals has migrated and continued growing in the inlay glaze.

In the third image there are a series of what appear to be small dark green acicular crystals overlaying
the white crystals. These are translucent, and a pale amber. The tint seen is the result of the image
manipulation that made them visible.

The matrix (i.e., background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three quarters of an inch.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.

The close-up images were heavily edited to enhance detail. The colors of the full image of the bowl
are as they appear in bright light.



Close up Images of the interaction region



Image of the piece

full view

bowl with glaze hiAlk_Z3P_Z4E and inlay glaze oribe-woof-black-M

bowl is ~6 inches in diameter



oxidation firing to a hot cone 10 in an electric kiln

Firing profiles

Up Fire profile hot cone 10

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

200 deg F an hour to 2220 deg F then a 90 min hold at 2220 deg F

90 deg F an hour to 2320 deg F

Down Fire Profile hot cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hr hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula hiAlk_Z3P_Z4E :

K2O        0.11
Na2O       0.50
CaO        0.37
MgO        0.02

Al2O3      0.57

SiO2       3.11
P2O5       0.06
TiO2       0.22

molecular percent Silica 62.7%



Inlay Glaze:

Empirical Formula oribe-woof-black-M

K2O        0.10
Na2O       0.04
CaO        0.69
MgO        0.17

Al2O3      0.38

SiO2       3.15
P2O5       0.01
ZrO2       0.05

molecular percent Silica 68.4%

Added:

5.0% Copper Oxide
0.75% Cobalt Carbonate



Remarks

This firing features a 'rounded at the top' firing profile; with a hold of an hour and a half at 100 degreesF
below top temperature, and a slow climb from there to the top temperature.

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