Glaze Interactions

This is a further exploration of a firing which has a slow up-fire in addition to having the usual
holds on the way down.

The matrix glaze is a high silica/low alumina gloss glaze containing zircon, densely
covered in micro-crystals. The inlay glaze is a titanium bearing saturated iron glaze, which
contributes its own distinct crystals.

Nearly the same combination of matrix glaze and inlay glaze has been seen here, without the
retarded up-fire, with greatly different results.

The slow up-fire allows micro-crystals to form in both matrix and inlay. These crystals migrate
across the boundary between the two glazes and also act as sites for the growth of foreign crystals,
providing a rich environment in which a multitude of distinct crystals can form.

That there are many distinct crystals formed within the interaction region is observed in the quantity
of distinct crystal morphologies seen. There are acicular crystals with radial spokes resembling the
underside of a mushroom. One sees continuity of color through crystals, indicating translucency.

In the third close-up, silvery metallic globules resembling molten metal are visible.

The formation of the nuclei, the sites for crystal, requires that the materials in the glaze slops
decompose, releasing their oxides to the melt. A slow approach to top temperature provides time
for this process.

The matrix (i.e., background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three quarters of an inch.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.

The close-up images were heavily edited to enhance detail. The colors of the full image of the bowl
are as they appear in bright light.



Close up Images of the interaction region

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Image of the piece

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bowl with glaze oribe-woof-PAlZr and inlay satIron_ZG_Z3N_Z4A+hiAlk_Z3P_Z4E

bowl is ~6 inches in diameter



oxidation firing to a hot cone 10 in an electric kiln

Firing profiles

Up Fire profile hot cone 10

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

200 deg F an hour to 2220 deg F then a 90 min hold at 2220 deg F

120 deg F an hour to 2320 deg F

Down Fire Profile hot cone 10

300 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hr hold at 1700 deg F

25 deg F an hour to 1650 deg F then a 1 hr hold at 1650 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula oribe-woof-PAlZr :

K2O        0.10
Na2O       0.03
CaO        0.71
MgO        0.16

Al2O3      0.41

SiO2       2.97
P2O5       0.01
ZrO2       0.11

molecular percent Silica 65.97%

Added:

5.0% Copper Oxide



Inlay Glaze:

Empirical Formula satIron_ZG_Z3N_Z4A+hiAlk_Z3P_Z4E:

K2O        0.13
Na2O       0.52
CaO        0.33
MgO        0.02

Al2O3      0.63
Fe2O3      0.11

SiO2       3.36
P2O5       0.07
TiO2       0.12

molecular percent Silica 63.6%



Remarks

This firing features a 'rounded at the top' firing profile; with a hold of an hour and a half at 100 degreesF
below top temperature, and a slow climb from there to the top temperature.

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