unrelated glazes at a vertical interface

Dissimilar glazes interacting at a vertical interface.

The matrix (i.e. background) glaze and inlay glaze overlap by no more than an eighth of an inch before firing,
with no overlap whatever for large parts of the design. The original mask for the inlay was a curved line,
nowhere more than three eights of an inch thick.

The matrix glaze is high in iron, alumina and alkali metals. The inlay glaze, by contrast,
is higher in Calcium, and contains Phosphorus.

Similar artifacts are seen here in the interaction between an unrelated background glaze, and the same foreground glaze.

Several closeups of the interaction region of the two glazes are shown and, for context, a picture of the pot.

The background glaze is iron_satIron_Z2W_Z2Z_0, the inlay design is glazed with satIron_ZG_1O_1Q_1MFe.

The design is created by adhering a mask and then applying the main glaze. After drying, the mask is removed
and the open area filled in with a second glaze, using a bulb syringe.



Close up Images of the interaction region

full view

full view

full view

full view



Image of the piece

full view

mug with glaze iron_satIron_Z2W_Z2Z_0 and inlay satIron_ZG_1O_1Q_1MFe

mug is ~4.5 inches in high



oxidation firing to cone 10 in an electric kiln

Firing profiles

Up Fire profile

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2310 deg F with a hold of 20 minutes at 2310 deg F

Down Fire Profile

300 deg F an hour to 1750 deg F then a half hour hold at 1750 deg F

300 deg F an hour to 1700 deg F then a Three hour hold at 1700 deg F

25 deg F an hour to 1650 deg F then a one hour hold at 1650 deg F

Clay body is a grolleg porcelain from Tacoma Clay Art Center.



glaze compositions

Background glaze

Empirical Formula iron_satIron_Z2W_Z2Z_0 :

K2O        0.10
Na2O        0.50
Li2O        0.26
CaO        0.03
MgO        0.11

Al2O3        0.66
Fe2O3        0.22

SiO2        3.4

molecular percent Silica 64.3%



Inlay Glaze

satIron_ZG_1O_1Q_1MFe :

K2O        .24
Na2O        .22
Li2O        .24
CaO        .16
MgO        .14

Al2O3        .47
Fe2O3        .09

SiO2        3.17
P2O5        .04

molecular percent Silica 66%



Remarks

The higher concentrations of Calcium and Phosphorus migrate from the inlay glaze into the matrix, seeding
additional phases in the matrix glaze.

In the interaction region, we see globules of a non-crystalline phase, yellow and red colored regions like oil
in salad dressing. These globules have sharp boundaries and are not otherwise seen in either matrix or inlay glazes.

Most of the increase in area covered by the inlay is attributable to dissolution of the matrix glaze
resulting from diffusion of inlay glaze into the matrix.

The mask for the inlay is a simple wiggly line. After firing, the inlay is considerably broadened.

Carol's Home Page