Glaze Reactions

With a similar firing profile and a small change in the matrix glaze, we show one more new face
of the interaction between a high titanium glaze and an oribe glaze. Here we see the matrix glaze
hiAlk_Z3P_Z4E with inlay glaze oribe-woof-PAl-PSiMg.

As above, the inlay design is glazed with oribe-woof-PAl-PSiMg.
However the background glaze is hiAlk_Z3P_Z4E_0MTi, a close relative of the former with a bit
less silica and also less titanium.

This firing, while also a cone 11 firing, has a lower final temperature and shorter hold at that temperature.

With this slight decrease in silica, the balance between when rutile micro-crystalline
clusters grow and copper migrates at an appreciable rate into the matrix glaze has shifted. The result
is that we have white titanium crystal clusters with black edges, and grey-black crystal cluster with
white edging. Clearly crystals grow, and copper migrates at the same time, and all is determined
by relative speed of growth vs. oxide movement in a particular region.

The black band edging the interaction region has reappeared. Much of the interaction region
is covered in a lacy black border of titanium crystals.

Additionally, we see micro-crystalline titanium clusters growing in the oribe-woof-PAl-PSiMg inlay.

All of this is the result of a small shift in the composition of the matrix glaze along with a change
in the firing profile. Undoubtedly the glaze application thickness also differed and had its effect.

The matrix (i.e., background) glaze and inlay glaze overlap minimally before firing. The width of the
original inlay varied from an eighth of an inch to three eighths of an inch.

The design is created by adhering a mask and then applying the main glaze. After drying,
the mask is removed and the open area filled in with a second glaze, using a bulb syringe
with a needle applicator.



Close up Images of the interaction region

full view

full view

full view

full view

full view



Image of the piece

full view

bowl with glaze hiAlk_Z3P_Z4E_0MTi and inlay oribe-woof-PAl-PSiMg

bowl is ~9.5 inches in diameter



oxidation firing to cone 11 in an electric kiln

Firing profiles

Up Fire profile cone 11

150 deg F an hour to 250 deg F

400 deg F an hour to 1800 deg F

300 deg F an hour to 2050 deg F

120 deg F an hour to 2320 deg F with a hold of 30 minutes at 2320 deg F

Down Fire Profile cone 11

300 deg F an hour to 1650 deg F then a 3 hr hold at 1650 deg F

400 deg F an hour to 1850 deg F then a 2 hr hold at 1850 deg F

300 deg F an hour to 1750 deg F then a 1 hr hold at 1750 deg F

300 deg F an hour to 1700 deg F then a 3 hour hold at 1700 deg F



Clay body is a grolleg porcelain from Clay Art Center in Tacoma, WA.



glaze composition

Empirical Formula hiAlk_Z3P_Z4E_0MTi :

K2O        0.10
Na2O       0.48
CaO        0.40
MgO        0.02

Al2O3      0.58

SiO2       2.99
P2O5       0.06
TiO5       0.19

molecular percent Silica 62.3%



Inlay Glaze:

Empirical Formula oribe-woof-PAl-PSiMg:

K2O        0.10
Na2O       0.04
CaO        0.61
MgO        0.25

Al2O3      0.35

SiO2       3.29
P2O5       0.01

molecular percent Silica 70.58%

Added:

5.0% Copper Oxide



Remarks

See prior note for details on the relative formation of colored and white titanium crystals.

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